Decoration of silver nanowires (AgNW) on stretchable textiles is considered a promising approach for fabricating flexible wearable textiles for electromagnetic interference (EMI) shielding applications. However, poor contact at wire junctions and adhesion of organic substrates negatively affect the overall textile performance, such as flexibility, resiliency, and electrical properties in dynamic-adaptive scenarios. In this study, we use poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) for welding AgNW junctions, adding additional conductive channels, and improving AgNW adhesion to the textile substrate. To this end, a durable electrospun polyurethane (PU) nanofiber mat was decorated with AgNWs and PEDOT:PSS with superior mechanical stability and electrical properties toward an applicable wearable textile for healthcare industries.